Technology topic

Hydrogen purification

Separate hydrogen concentration from fuel quality. Compare PSA and membranes, recovery, pressure and trace-contaminant requirements.

Start with a gas specification

Hydrogen purification removes unwanted constituents from a hydrogen-containing stream. Pressure swing adsorption retains impurities on adsorbents. Membranes separate through material-specific transport. The preferred arrangement depends on feed composition and the product required.

Purity and recovery answer different questions. A highly pure product can contain only a fraction of the hydrogen entering the separator. Product pressure is another independent requirement, especially where the next step is storage or compression.

The word membrane covers polymers, porous inorganic materials and dense metals with different operating conditions and selectivities. A dense palladium layer transports hydrogen through the metal; it does not act as an ordinary porous screen.

For a PEM fuel cell, a total purity percentage is insufficient. Trace carbon monoxide and sulfur have different effects from an inert diluent. Specify individual analytes, their limits and a measurement method that reaches those limits.

The comparison guide explains PSA and membrane process choices. The fuel-quality guide follows the purified stream to its user, distinguishing older published threshold examples from the current ISO 14687 edition.

Terminology is defined in the technical glossary. Source material is linked below.

Side-by-side separation processes: PSA retains impurities in adsorbent beds, while a selective membrane sends hydrogen to a lower-pressure permeate stream.
Original conceptual illustration by FluidCell.eu Editorial. Image details and licence.

Read the guides

Sources & further reading

  1. Recent Advances in Membrane-Based Electrochemical Hydrogen Separation: A Review (2021)Membranes, 11(2), 127 · Open access, CC BY 4.0. PSA, pressure-driven membranes and electrochemical separation.
  2. Alique et al. (2018). Review of Supported Pd-Based Membranes Preparation by Electroless Plating for Ultra-Pure Hydrogen ProductionMembranes, 8(1), 5 · Open access, CC BY 4.0. Thin films, supports, transport and failure mechanisms.
  3. Gas standards brochure (2023): hydrogen purityNational Physical Laboratory · Illustrative ISO 14687 impurity thresholds and traceable analytical methods. Use the applicable current standard for a procurement specification.
  4. ISO 14687:2025: Hydrogen fuel quality — Product specificationInternational Organization for Standardization